Haechan Kim

KITECH, the Republic of KOREA



Biography

He has a passion for developing new materials using polymer synthesis. He is focusing on developing various materials with a sense of purpose in creating high value-added products through the development of new materials. He is currently working for the Korea Institute of Industrial Technology (KITECH) in the Republic of Korea and is in master’s course in Hanyang University.

Abstract

To disperse silica in SBR matrix, a need for adequate dispersant is long-standing. Proper interactions between SBR and silica are important for improving silica dispersibility between SBR and silica in medium. We prepared poly(glycidyl methacrylate-co-styrene) copolymer as a reactive dispersant by emulsion copolymerization using the sodium persulfate/ iron sulfate redox system. The structure of poly (GMA-co-styrene) is an amphipathic copolymer composed of phenyl group and epoxy group. The glycidyl group of GMA and silanol one of Si formed a covalent bond resulting in improving the dispersion of silica in Si-SBR composites. We suggested a possible reaction mechanism for our system. We confirmed the structure of poly(GMA-co-styrene) copolymer using FT-IR spectroscopy. Also, we investigated dispersion effects in Si- SBR composites according to the input molar ratio of monomer in copolymer and content of initiator.